If your desired mime type isn't supported by default. You can add it for your own by modifying your .htaccess file in your main web directory (/www).
Example:
Let's assume, that *.zip isn't supported by the configuration file below.

Then you would add the following line to your .htaccess file:
AddType application/zip    zip

WARNING: Be very careful editing your .htaccess files. Even a minor typographical error can make your site unusable!
Always make a backup copy of the file so you can recover quickly.

Our Mime configurations:

text/vnd.wap.wml                  Wml
application/vnd.wap.wmlc          Wmlc
text/vnd.wap.wmlscript            Wmls
application/vnd.wap.wmlscriptc    Wmlsc
image/vnd.wap.wbmp                wbmp
text/x-hdml                       hdml
image/png                         png
image/bmp                         bmp
image/x-freehand                  fh4 fh7 fh5 fhc fh
chemical/x-gaussian-cube          .cube .cub
chemical/x-rasmol                 scr
chemical/x-jcamp-dx               jdx jx
chemical/x-mdl-molfile            mol
chemical/x-mdl-tgf                tgf skc
chemical/x-mdl-rxnfile            rxn
chemical/x-pdb                    pdb
chemical/x-gaussian-input         gau
chemical/x-xyz                    xyz
chemical/x-mopac-input            mop
chemical/x-embl-dl-nucleotide     emb embl
chemical/x-csml                   csm csml
application/x-spt                 spt
application/x-authorware-map      aam
application/x-httpd-Miva          mv hts htmv
application/x-ipscript            ips
application/font-tdpfr            pfr
application/x-ipix                ipx
application/x-javascript          js
application/vocaltec-talker       vtk
application/hstu                  stk
application/x-mathcad             mcd
application/commonground          dp
application/x-cprplayer           pqf
application/cprplayer             pqi
application/presentations         shw
application/x-authorware-seg      aas
application/x-authorware-bin      aab
application/msword                doc
application/x-cult3d-object       co
drawing/x-dwf                     dwf
application/dsptype               tsp
application/x-twinvq              vqf vql
application/x-7th_level_event     7ls 7lp 7le
application/x-twinvq-plugin       vqe
application/x-director            dcr dir dxr
application/x-shockwave-flash     swf
application/smil                  smi smil
application/x-pn-realmedia        rp smi smil
application/activemessage
application/x-envoy               evy
application/andrew-inset
application/applefile
application/atomicmail
application/dca-rft
application/dec-dx
application/excel                 xls
application/futuresplash          spl
application/mac-binhex40          hqx
application/x-stuffit             sit sea
application/macwriteii
application/mbed                  mbd
application/mirage                mfp
application/msword
application/news-message-id 
application/news-transmission
application/octet-stream          bin exe
application/oda                   oda
application/pdf                   pdf
application/postscript            ai eps ps
application/quest                 qrt
application/remote-printing
application/rtf                   rtf
application/slate
application/toolbook              tbk
application/x-chat                chat
application/x-director            dcr dir dxr
application/x-mif                 mif
application/x-sprite              spr
application/wita
application/wordperfect5.1
application/vocaltec-media-desc   vmd
application/vocaltec-media-file   vmf
application/x-csh                 csh
application/x-dvi                 dvi
application/x-hdf                 hdf
application/x-latex               latex
application/x-netcdf              nc cdf
application/x-sh                  sh
application/x-tcl                 tcl
application/x-tex                 tex
application/x-texinfo             texinfo texi
application/x-troff               t tr roff
application/x-troff-man           man
application/x-troff-me            me
application/x-troff-ms            ms
application/x-wais-source         src
application/zip                   zip
application/x-bcpio               bcpio
application/x-cpio                cpio
application/x-gtar                gtar
application/x-midi                mid
application/x-shar                shar
application/x-sv4cpio             sv4cpio
application/x-sv4crc              sv4crc
application/x-tar                 tar
application/x-ustar               ustar
application/x-director            dir
application/x-director            dcr
application/x-director            dxr
audio/basic                       au snd
audio/midi                        mid
audio/voxware                     vox
audio/x-aiff                      aif aiff aifc
audio/x-mid                       mid
audio/x-midi                      mid
audio/x-mpeg                      mp2 mp3 m1a 
audio/x-mpegurl                   mpu m3u
audio/x-wav                       wav
image/cis-cod                     cod
image/vn-svf                      svf
image/fif                         fif
image/gif                         gif
image/ief                         ief
image/jpeg                        jpeg jpg jpe
image/tiff                        tiff tif
image/x-cmu-raster                ras
image/x-portable-anymap           pnm
image/x-portable-bitmap           pbm
image/x-portable-graymap          pgm
image/x-portable-pixmap           ppm
image/x-rgb                       rgb
image/x-xbitmap                   xbm
image/x-xpixmap                   xpm
image/x-xwindowdump               xwd
image/CEWavelet                   wif
image/png                         png
image/x-png                       png
image/pict                        pic
message/external-body
message/news
message/partial
message/rfc822
multipart/alternative
multipart/appledouble
multipart/digest
multipart/mixed
multipart/parallel
multipart/form-data
text/html                         html htm tpl
text/plain                        txt
text/richtext                     rtx
text/tab-separated-values         tsv
text/x-setext                     etx
text/xml                          xml
ulead/vrml                        uvr
video/x-ms-asf                    asf
video/mpeg                        mpeg mpg mpe
video/quicktime                   qt mov
video/x-msvideo                   avi
video/x-sgi-movie                 movie
video/vivo                        viv vivo
video/vdo                         vdo
audio/x-pn-realaudio              ra ram rm
audio/x-pn-realaudio-plugin       rpm
x-world/x-vream                   vrw
x-world/x-vrml                    wrl
i-world/i-vrml                    ivr
x-world/x-d96                     d-96 mus
x-world/x-svr                     svr
video/vnd.vivo                    vivo viv
text/x-speech                     talk

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- Last modified on 3/16/2003 -